SECOND
YEAR CHEMCIAL ENGINEERING
SEMESTER
– III
1.
ENGINEERING MATHEMATICS - III
Teaching
Scheme Examination Scheme
Lectures
: 3 hours/week Theory : 100 marks
Tutorial
: 1 hour/week Term work: 25 marks
SECTION
-1
Unit
1 Greens Function: Greens Function for ordinary
differential equation. Initial value problem,
Final
value problem, Construction of Greens function for ordinary differential
equations.
Unit
2 Linear Differential Equations: Linear
Differential Equations with constant coefficients,
Homogenous
Linear differential equations, Applications of LDE with constant coefficients
to
chemical
engineering problem.
Unit
3 Differential Equations Applications: Applications
of Differential Equations of first order to
geometry,
Trajectories. Application of Linear differential equations to chemical
Engineering
problems.
SECTION-II
Unit
1 Laplace Transform: Definition, properties of
Laplace transforms, transforms of derivatives,
transforms
of integral, Periodic function, Convolution theorem. Inverse transform,
Applications to
initial
value boundary problems
Unit
2 Vector Differentiation: Differentiation
of vectors, normal and tangential components of velocity
and
acceleration, Gradient of scalar point function, Directional derivative,
Divergence of vector
point
function, Curl of a vector point function. Irrotational and solenoid vector
field.
Unit
3 Vector Integration: The line integral, Surface
integral, volume integral, Gauss's Divergence
theorem,
Stoke's theorem, Green's theorem (Without proof). Irrotational and solenoidal
vector
field.
General
Instructions:
1.
For the term work of 25 marks, batch wise tutorials are to be conducted. The
number of
students
per batch should be as per university pattern for practical batches.
2.
Minimum number of assignments should be 8 covering all topics.
Nature
of Question paper:
1.
There will be two sections carrying 50 marks each.
2.
There will be four questions in each section and three questions should be
attempted from
each
section.
Reference
Books:
1.
A text book of Applied Mathematics: Vol. I, II and III by J. N. Wartikar &
P. N. Wartikar,
Vidyarthi
Griha Prakashan, Pune.
2.
Higher Engineering Mathematics by Dr. B. S. Grewal.
3.
Advanced Engineering Mathematics by Erwin Kreyszig.
4.
Operations Research by S. D. Sharma
5.
Operations Research by T. A. Taha
6.
Mathematical Methods in Chemical Engineering by S.Pushpavanam.
2.
Chemistry –I
Teaching
scheme Examination scheme
Lectures
:- 4 hrs. / week Theory : 100 marks
Practicals:
- 4 hrs /batch/week Term work: 50 marks
Practical
/ Oral: 50 marks
Section
–I
1.
Chemical kinetics: (4 lectures)
Introduction,
order and molecularity of reaction, rates of reaction, first and second order
reactions
with derivation, Theories of reaction rates- collision and transition state
theory, pseudo
unimolecular
reactions, determination of rates of reaction, numericals.
2.
Distribution law: (4 lectures)
Introduction,
Nernst distribution law, solubility and distribution law, explaination &
limitations
of
distribution law, Henry’s law, determination of equilibrium constant from
distribution
coefficient,
numericals.
3.
Photochemistry: (4 lectures)
Introduction,
laws of photochemistry, quantum efficiency, kinetics of photochemical
reactions,
photochemical
equilibrium, photosensitized reactions, photochemical phenomenon,
photosynthesis.
4.
Phase equilibrium: (4 lectures)
Introduction,
concept & terminology, Gibbs phase rule with derivation, one component
system
(sulpher), two component system (Zinc-Cadmium), phase diagram of solid
solutions.
5.
Catalysis: (4 lectures)
Definition,
characteristics, types- homogeneous & heterogeneous, theory of catalysis,
catalystacid
/
base, solid catalysts like oxides, metal & zeolites, phase transfer
catalysts, enzyme
catalysts
(biocatalysts), mechanism of catalysis, concept green chemistry with examples
Section
II
6.
Chemistry of dyes and dye intermediates : (4 lectures)
Colour
and chemical constitution, chromophore- auxochrome theory, valency bond theory,
classification
of dyes based upon structure & methods of application, synthesis and
applications of
malachite
green, methyl orange, alizarine & phenolphthalein.
7.Soaps
and detergents (4 lectures)
Soaps
and saponification, cleansing action of soaps, manufacture of soap by modern
process,
detergents, classification, cleansing action, manufacture of anionic detergents
(D.B.B.S.)
8.Drugs
and pesticides: (4 lectures)
Drugs-Chemotherapy,
synthesis and mode of action of sulpha drugs( sulphanilamide),
antibiotics
(chloramphenicol), analgesics (paracetamol).
Pesticides-
Introduction, classification, synthesis, properties and uses of BHC, DDT,
Malathion.
9.Microbiology
& biomolecules: (4 lectures)
Structure
and composition of cell, molecules of life. Biomolecules- Proteins, Enzymes,
Nucleic
acids
(Structure, role & functions)
10.Unit
processes in organic synthesis: (4 lectures)
Introduction,
types of processes.
Nitration-
Nitrating agents, mechanism of aromatic nitration, industrial nitration of
benzene to
nitrobenzene
by continuous processes.
Oxidation-
Types of oxidation reactions, oxidizing agents, mechanism of oxidation,
manufacture of
acetic
acid by oxidation of acetaldehyde.
Chemistry
– I
PRACTICALS
(Minimum
18 experiments should be completed)
1.
Determination of reaction rate constant of catalysed hydrolysis of methyl
acetate
in
N/2 HCl
2.
Determination of reaction rate constant of catalysed hydrolysis of methyl
acetate
3.
in N/2 H2SO4
4.
To determine partition coefficient of benzoic acid in benzene and water.
5.
To determine partition coefficient of iodine in carbon tetrachloride and water.
6.
Determination of reaction rate constant of reaction between K2S2O8 & KI
7.
Determination of reaction rate constant of reaction between H2O2
& HI
8.
Laboratory preparation of phenol formaldehyde resin.
9.
Laboratory preparation of aspirine (acetyl salicylic acid)
10.
Laboratory preparation of soap
11.
Determination of saponification value of the given oil sample
12.
Laboratory preparation of m-Dintrobenzene from benzene
13.
Preparation of methyl orange
14
-19 Identification of monofunctional and bifunctional organic compounds
(minimum 6
compounds)
REFERENCE
BOOKS (Chemistry –I)
Organic
chemistry
1.
Organic chemistry – Volume I& II- Finar & Finar (English language book
society-1989)
2.
Organic chemistry -- Fieser & Fieser
3.
Organic chemistry -- Bhal & Bhal(S. Chand -2000)
4.
Organic chemistry -- P.L. Soni (S. Chand -1994)
5.
Organic reactions and mechanism – Pitter Sykes (Orient Longman-1986)
Physical
chemistry
1.
Physical chemistry -- Puri & Sharma (Shobanlal Nagin Chand - 2005)
2.
Essentials of Physical chemistry -- Bhal & Tuli (S. Chand & Co. - 2005)
3.
Principles of Physical chemistry--Prutton & Maron (oxford & IBH
Publishing Co. Pvt. Ltd
1972)
4.
Text book of physical chemistry - Gladstone (Macmillan India Ltd. - 1995)
Reference
books for Practicals
1.
Practical organic chemistry -- A. I. Vogel (CBS-1987)
2.
Experiments in applied chemistry –Sunita Rattan (S. K. Kataria & Sons-
2002)
3.
STRENGTH OF MATERIALS AND MATERIALS OF CONSTRUCTION
Section
–I
Teaching
Scheme Examination Scheme
Lectures
: 3 hours / week Practical : 2 hrs/week
Term
Work :
Internal
: 25 Marks
Strength
of materials
1.
Introduction to strength of materials : Equilibrium of rigid beam under general force
system,
concept of stress, simple stresses and strain, ultimate and working stress,
Properties
of materials, elastic constant relation between elastic constants, compound
bars,
temperature stresses.
2.
Analysis of two-dimensional stress system : Principal stresses, Mohr's circle of Stress.
3.
Torsion of shafts : Torsion
equation, strength and stiffness of solid and hollow circular
shafts.
Transmission of power.
4.
Thin cylindrical and Spherical shells : Subjected to fluid pressure wire wound cylinders.
5.
Thick Cylinder :
Lamis theory, Design of thick cylindrical shell, Thick Spherical Shells.
6.
Direct and bending stresses : Introduction, Direct and eccentric loading, limits of
eccentricity,
core of section, wind pressure.
Section
– II
Materials
of construction
7.
Introduction
8.
Introduction to Mechanical properties of materials
9.
Selection of right material
10.
Materials Failure
11.
Materials standards and specifications
12.
Economics in material selection.
13.
Materials available :
a)
Ferrous metals, alloys and fabrication characteristics
b)
Non-ferrous metals , alloys and fabrication characteristics
c)
In organic Nonmetallic Glass & Glass steel, Porcelain and stoneware,Cement
and
concrete,
Soil, Asbestos & rock wool.
d)
Organic Non-metallic: Thermoplastics, Thermo-setting plastics, Rubber &
Elastomers,
Asphalt,
Carbon and Graphite, wood.
e)
Coatings, Lining/ cladding
f)
High & Low temperature materials
g)
Comparison of various materials
14.
Corrosion : a)
Types of corrosion - Galvanic corrosion, Crevice corrosion,
Erosion
corrosion, Stress corrosion.
b)
Corrosion Prevention- Material selection, Coatings, Economics.
Term
Work :
1.
Tension test on mild steel.
2.
Compression test on mild steel and timber
3.
Hardness test – brinell and rockwells
4.
Torsion test
5.
Inpact test charpy and izod.
6.
Shear test-double shear
References
:
1.
Punmia B.C. ‘Strength of Materials and Mechanics of Structure’-Vol.I- Standard
Publications,
Delhi.
2.
C. Patel, T.D. Bhagia, ‘Strength of Materials ’ Vol. I, C. Jamnadas & Co.
Mumbai
3.
Ramamruthm, ‘Strength of Materials’ , - Dharapatray & Sons, Delhi , 1998.
4.
Sarkar B.K. ‘Strength of Materials’, -- Allied Publishers, New Delhi , 2001.
5.
William Nash, ‘Strength of Materials’, IVth Ed. McGraw Hill Publication.
MATERIALS
OF CONSTRUCTION
Reference:
1.
Bhattacharya B.C., ‘Selection of materials and fabrication for Chemical Process
Equipment,
Chemical Engg.’ , Educational Development Centre , IIT Madras
2.
Coulson & Richardson ‘Chemical Engineering’, Volume VI, Pergamen Press .
3.
Robert N. Perry & Don Gress , ‘Perry's Chemical Engineers Handbook’, VIth ed. McGraw
Hills
International Ed. Newyork 1984.
4.
D. Venkateswarlu & other, Chemtech -I, ‘First volume of manual of Chemical
Technology’,
Chemical Engg. Educational Development Centre, IIT Madras.
5.
Corrosion Engineering IIndedition Mars G.Fontana.
4.
FLUID MECHANICS
Section
– I
1.
Unit systems : Physical
quantities, S.I., CGS, FPS engg. units, Conversion of Units,
Units
and Equations, dimensional analysis, Application of dimensional analysis,
Problems.
2.
Fluid statics and its applications : Nature of fluids, Hydrostatic equilibrium,
Barometric
equation, Hydrostatic equilibrium in centrifugal field, Manometers, Example,
U
tube, Inclined tube manometers.
3.
Fluid flow phenomena : Behaviour of flowing fluid, Types of flow, Newtonian and non-
Newtonian
Fluids, viscosity and momentum flux, viscosities of gases and liquids,
Turbulence,
Reynolds experiment, Eddy viscosity, Flow in boundary layers, Laminar and
Turbulent
flow in Boundary layers, Boundary layer formation in straight tubes, Boundary
layer
separation and wake formation.
4.
Basic equations of fluids flow : Mass balance, mass velocity, momentum balance,
Bernoulli's
equation without and with friction, kinetic energy correction factor,
correction
for
fluid friction, Pump bernoulli's equation , Eulers equation, Problems.
5.
Flow of incompressible fluids in conduits and thin
layers : Shear stress distribution
in
a cylindrical tube, relation between skin friction and wall shear, the friction
factor.
Relations
between skin friction parameters. Laminar flow in pipes, Laminar flow of
Newtonian
fluids. Average velocity, kinetic energy correction factor (Derivation),
Momentum
correction factor (Derivation), Hagen-poiseuilie equation. Turbulent flow in
pipes
and closed channels. Velocity distribution for turbulent flow, universal
velocity
distribution
equations for laminar sub layer and buffer layer, Relations between maximum
and
average velocities, Effect of roughness,The friction factor chart ( Moody's
diagram),
friction
factor in flow through channels of non-circular section, friction from changes
in
velocity
or direction, Effect of fittings and valves, couette flow, Layer flow with free
surfaces
, Flow through annulas, Problems.
Section
– II
6.
Flow of compressible fluids : Mach number, continuity equation,Total energy Balance,
velocity
of sound, ideal gas equations, the asterisk condition, stagnation temperature.
7.
Transportation and metering of fluids : Pipe and tubing, joints and fittings.
Prevention
of leakage around moving parts. Valves- Gate valve, globe valve, check valve
butterfly
valve, needle valve, ball valve etc. Measurement of flowing fluids.
Venturimeter,
orificemeter,
pitot tube, rotameters, target meters, vortex- shedding meters, turbine
meters,
positive displacement meters, magnetic meters: ultrasonic meters.
8.
Flowpast immersed bodies : Drag coefficients of typical shapes, form drag and stream
lining,
Friction in flow through beds of solids, Erguns equation, Kozeny- Carman
equation,
Burke
Plummer equation, Fluidization, Mechanism of fluidization, particulate and
aggregative
fluidization, minimum fluidization velocity, expansion of -fluidized beds,
application
of fluidization.
9.
Agitation of fluids : Agitation
of liquids, Agitation equipment, flow patterns in agitated
vessels,
circulation rates, Flow numbers, power consumption, power correlations, power
correlations
for specific impellers, effect of system geometry and calculations for power
consumption.
Term
Work :
1.
Venturimeter 6. Flow through annular pipe
2.
Orifice meter 7.Flowthrough pipe & pipe fittings.
3.
Reynold’s experiment 8. Flow through spiral coils.
4.
Bernoulli’s experiment 9. Flow through packed bed
5.
Flow through helical coils 10. Flow through fluidized bed.
11.To
study the properties of Newtonian and Non- Newtonian fluids.
12.Demonstration
of –
a)
Rotameter
b)
Pitot tube
13.
Two phase flow system
Text
Book:
1.
Mc Cabe W.L. and Smith J.C. ‘Unit operations of Chemical Engg.’ VII ed. Mcgraw
Hill Book
Co.,
International ed. 1993
References:
Steeter
U.L, ‘Fluid Mechanics’ V ed. Mc graw Hill Book Co., International Edn.1971.
Richardson
J.E. and Coulson J.M. Chemical Engg. 3rd ed. Vol. 1 Pergamon Press
1985.
Miohell
B.I. Fluid and Particle Mechanics Pergamon Press 1970.
4
Gupta S.K., Momemtum Transfer Operations, Tata McGraw Hill, 1979.
5.
Mechanical Operations
Lectures:
3 hrs Theory: 100 marks
Practical:
2 hrs / batch / week Practical:
External-
25 marks
Internal-
25 marks
Section
I
1.
Properties and handling of particulate solids
Particle
characterization, Particle size measuring technologies, Particle size
distribution,
Mean
particle size, Mixed particle sizes and shape. Properties of solid masses,
Storage of
solids
(Bulk and Bin), Flow through Hoppers, Angle of repose and angle of friction,
Introduction
to conveying of solids. (4 Lectures)
2
Size reduction
Mechanism
of size reduction, Energy for size reduction, Crushing laws, Methods of
operating
crushers, Classification of size reduction equipments, Types of crushing
equipment,
Factors affecting communiation, Heat control methods in size reduction.(5
Lectures)
3
Screening
Standard
test screens, Standards of screen, Screen effectiveness, Comparison of ideal
and
actual
screens, Industrial screening equipment. (3 Lectures)
4
Mixing of solids and pastes
The
degree of mixing, Rate of mixing, Criteria for mixer effectiveness,
Solid-liquid mixing,
Mixing
for paste and plastic masses, Solid-Solid mixing. (2 Lectures)
Section
II
5
Filtration
Classification
of filtration, Types of filtration, Pressure drop through filter cake, Filter
medium
resistance, Sp.cake resistance, Washing of cake, Filter media and selection,
Compressible
filter cakes, Preliminary treatment of slurries before filtration, Filtration
equipment,
Filter selection, Filter press, Vacuum filters, Centrifugal filtration and
Filtration
calculations.(8
Lectures)
6
Sedimentation
Basic
principles, Flocculation, Thickeners, Batch sedimentation test, Design
procedure for
gravity
sedimentation tanks. (4 Lectures)
7.
Gas Cleaning
Introduction,
Gas cleaning equipment, Gravity separators, Centrifugal separators,
Momentum
separators, Electrostatic precipitators, Liquid washing, Odour removal, Fabric
filters,
Impingement method and Miscellaneous methods, Agglomeration and Coal
essence.(5
Lectures)
8
. Benefaction Process in Chemical Engineering
Froth
flotation, Magnetic separators, Scrubbers, Jig classification, Heavy medium
separation,
Wilfiley table, Gravity settling tank. (3 Lectures)
Practicals:
Any
10 Practicals should be conducted.
1.
Sieve Analysis
2.
Screen Effectiveness
3.
Jaw Crusher
4.
Pulverizer
5.
Ball mill
6.
Sedimentation(Batch)
7.
Beaker Decantation
8.
Filter Press
9.
Leaf Filter
10.
Cyclone Separator
11.
Air Elutration
12.
Rotary Drum Filter
Demonstration
of following equipment and include in journal
1.
Riffled Table
2.
Mineral Jig
3.
Froth Flotation
Industrial
Visit:
Industrial
visit to Sugar industry, Distillery industry or any other chemical industry.
Visit
report should be submitted inclusive of following topics conveying, screening,
filtration,
cyclone
separator, crusher etc.
Text
Book
1.
Mccabe W.L. & Smith J.C. and Peter Harriott, Unit Operations of Chemical
Engg. 5th ed.,
Mcgraw
Hill International.
2.
C.M.Narayanan, B.C.Bhattacharyya, Mechanical Operations for Chemical Engineers,
Computer
Aided Analysis, Khanna Publishers.
3.
J.F.Richardson & J.H.Harker with J.R.Backhurst, coulson & Richardson’s,
Chemical
Engineering,
vol 2,1st ed., Pergamon Press.
References:
1.
Foust A.G. et.a- Principles of Unit Operations, 3nd
ed. John, Wiley & Sons, New
York
1979.
2.
G.C.Sekhar, unit Operations in Chemical Engineering, Pearson education
(Singarore) Pte.
Ltd.
6.
COMPUTER PRACTICE - I
Teaching
Scheme Examination Scheme
Lectures
: 1 hours / week Practical : 2 hrs/week
Term
Work :
Internal
: 50 Marks
1.
Introduction to operating system :
A)
MS -DOS
B)
Unix
C)
Novel Net work
2.
Programming in "C "
i.
Functions : Defining and accessing, passing, arguments, fuction prototype,
recursion,
Use of Library Functions.
ii.
Storage classes : Auto static, external register.
iii.
Structures.
iv.
Arrays.
v.
File Handling in C.
Term
Work :
1.
To practice unix command
2.
Making contact with Unix Login and Logout producer.
3.
Practice commands like CAT, PG, PR, LE, CP, MV, RM, WC, CH, MODE, DIFF,
GREP,
SORT, TEXT.
4.
To practice Novel network commands.
5.
To practice FoxPro commands.
6.
Database structure creation.
7.
Use of editor and working with command window.
8.
Quadratic equations
9.
Small and Large numbers
10.
Ascending and Descending order
11.
Fibonacci numbers
12.
Matrix addition , Substraction and multiplication.
Text
Books:
1.
Yashwant Kanitkar, Let us C, 4th Revised ed. BPB Publication, 1991.
2.
E. Balagurusamy , Programming in ANSY C, 2nd ed. Mc-Graw Hills Publishing Co. 1989.
3.
K.R. Venugopal and Sudeep R. Prasad , Programming with c, Mc-Graw Hills
Publishing
Co.
1997.
References:
1.
Byron Gottfried , Programming with C , Mc-Graw Hills Publishing Co. 1998
2.
Sumitabha Das, Unix Concepts and Applications, 2nd
ed., Mc-Graw Hills Publishing Co.
1998
3.
Microsoft Ms-Dos Users Guide
4.
Unix Users Guide manual
5.
Novel Network Users Guide
SEMESTER
– IV
1. ENGINEERING MATHEMATICS – IV
2.
Teaching
Scheme Examination Scheme
Lectures
: 3 hours/week Theory : 100 marks
Tutorial
: 1 hour/week Term work: 25 marks
SECTION
-1
Unit
1 Curve Fitting: Fitting of Curves by method
of Least-squares, Coefficient of correlation,
Spearman's
rank correlation coefficient and lines of regression of bivariate data
Unit
2 Probability: Random variable, Probability
mass function and probability density function,
Binomial,
Poisson and Normal distributions
Unit
3 Numerical solution of Partial differential equations: Transformation of partial differential
equation
into Difference equation and solution of Laplace equation by using Jacobi and
Gauss-
Seidal
method
SECTION-II
Unit
1: Partial differential equations: Linear
partial differential equation (Lagranges form). Non
linear
partial differential equations and its four standard forms.
Unit
2: Application of partial equation variable separation method:
Application
of P.D Equation to:-
1)
Wave equation (vibration of string)
2)
One dimensional heat flow.
3)
Two dimensional heat flow
Unit
3 Fourier series: Definition, Euler's formulae,
Dirchlet's Conditions for a Fourier expansion,
Functions
having points of discontinuity, change of interval, expansions of odd and even
periodic
functions, Half range series.
General
Instructions:
1.
For the term work of 25 marks, batch wise tutorials are to be conducted. The
number of
students
per batch should be as per university pattern for practical batches.
2.
Minimum number of assignments should be 8 covering all topics.
Nature
of Question paper:
1.
There will be two sections carrying 50 marks each.
2.
There will be four questions in each section and three questions should be
attempted
from each section.
Reference
Books:
1.
Mathematical Methods in Chemical Engineering by S.Pushpavanam.
2.
A text book of Applied Mathematics: Vol. I, II and III by J. N. Wartikar &
P. N. Wartikar,
Vidyarthi
Griha Prakashan, Pune.
3.
Higher Engineering Mathematics by Dr. B. S. Grewal.
4.
Advanced Engineering Mathematics by Erwin Kreyszig.
5.
Fundamental of Statistics by S. C. Gupta
6.
Numerical methods by Dr. B. S. Grewal
7.
Numerical methods by S. S. Sastry.
2.
Chemistry – II
Section
–I
1.Structure
and bonding : (4 lectures)
Molecular
orbital & valence bond approaches for diatomic molecules, hybridization
& structure
of
H2O, NH3, BF3, SF6, PCl5.
2.
co-ordination chemistry(5 lectures)
Introduction,
difference between double salt and complex salt, classification, werners
coordination
theory, effective atomic no. (EAN), valence bond theory and crystal field
theory for
octahedral
complexes.
3.
Inorganic heavy industries(4 lectures)
Manufacture
of H2SO4( contact process), NH3 (Habers process) w.r.t.
reactions, reactants,
catalyst
and physicochemical principles.
4.
Nonaqueous solvents(4 lectures)
Introduction,
classification of solvents, characteristic properties of solvents(mp. and
bp.,heats
of fusion and vaporization, dielectric constant), liquid ammonia and liquid HF,
reactions
of
liquid ammonia-precipitation, acid –base, oxidation- reduction, ammonolysis,
reactions of HFprecipitation
,
acid- base, protonation of organic compounds.
5.
Analytical chemistry(3 lectures)
Volumerty,
standards, concentration of solutions( molarity, normality, molality,
equivalent
weight,
strength of solution), normality equation, numericals based on calculation of
strength.
SECTION
–II
6.Named
organic reactions(4 lectures)
Mechanism
in brief and industrial applications of Friedal crafts reactions, Mannich
reaction,
Gatterman
Koch reaction, Claisen rearrangement, Benzidine rearrangement, Diels Alder
reaction,
aldol
condensation, Kolbe synthesis.
7.Spectroscopy(4
lectures)
Basic
principles, instrumentation and applications of I.R. spectroscopy, N.M.R.
spectroscopy.
8.Chemistry
of petroleum(4 lectures)
Origin
of crude, composition , refining of crude, cracking –catalytic cracking- batch
process
and
continuous process, major petrochemicals like ethelene propylene butadiene,
benzene
toluene,
(industrial applications only)
9.Polymers(4
lectures)
Polymers-definition,
polymerization techniques ( bulk, solution, suspension and
emulsion).
Plastics-compounding,
preparation, properties and applications of Acrylics,Teflon,
polymethyl
methacrylate, Buna- S rubber, Buna-N rubber, Butyl rubber.
10.Chemistry
of heterocycles(4 lectures)
Introduction,
classification, preparation, properties and applications of pyrrole, furan,
thiophene,
pyridine,quinoline, isoquinoline.
Chemistry
– II
PRACTICALS
(Minimum
18 experiments should be completed)
1-3.To
prepare standard solution of alkali, acid and to estimate the purity of
commercial
heavy
chemicals like H2SO4, HNO3, NH3.
4.
Preparation of Hexanitrocobaltate.
5.
Preparation of Hexammine cobaltic chloride.
6.
To prepare standard solution of sodium thiosulphate & to estimate copper
from brass
solution.
7.
To prepare standard solution of potassium dichromate & to estimate Iron
from ammonium
sulphate
using external indicator.
8.
To prepare standard solution of potassium dichromate & to estimate Iron
from ammonium
sulphate
using internal indicator.
9.
Estimation of nitrogen from given fertilizer solution.
10.To
prepare standard solution of EDTA & to estimate magnesium from given
dolomite ore
solution.
11.To
prepare standard solution of KMnO4 & to estimate Oxalic acid.
12.Estimation
of copper by colorimetric method.
13.Estimation
of Nickel by colorimetric method.
14.Laboratory
preparation of phenol formaldehyde resin.
15.Estimation
of Phenol
16.Estimation
of Aniline
17.Estimation
of Acetone
18.Estimation
of Acetamide
19.Estimation
of Glucose
REFERENCE
BOOKS (Chemistry –II)
Organic
chemistry
1.
Organic chemistry – Volume I& II- Finar & Finar (English language book
society-1989)
2.
Organic chemistry -- Fieser & Fieser
3.
Organic chemistry -- Bhal & Bhal(S. Chand -2000)
4.
Organic chemistry -- P.L. Soni (S. Chand -1994)
5.
Organic reactions and mechanism – Pitter Sykes (Orient Longman-1986)
Inorganic
chemistry
1.
Inorganic chemistry- Cotton & Vilkinson (Wiley Estern Ltd-1985)
2.
Inorganic chemistry – Dey & Selbin
3.
Advanced inorganic chemistry – Puri & sharma(Shobanlal Nagin Chand - 1996)
Reference
books for Practicals
1
Inorganic chemistry -- A. I. Vogel
2.
Practical organic chemistry -- A. I. Vogel (CBS-1987)
3.
Experiments in applied chemistry –Sunita Rattan (S. K. Kataria & Sons-
2002)
3.
Process Calculations
Lectures
: 4 hrs per week Examination:
Theory
: 100 marks
Term
Work : 25 marks
1.
Basic Chemical Calculations. (4)
Units
and Conversions, Pressure, Temperature, Density, Specific Gravity; Mole
Concept,
Equivalent
Weight, Composition of solids, Liquids and Gases, Mass fraction, Mass percent,
Mass
Ratios,
Mole fraction, Mole percent, Volume fraction and Volume percent, Normality,
Molarity ,
Molality.
2.
Gases Systems. (4)
Gaseous
mixtures, Daltons law, Amagats law, Average molecular weight, Density of
gaseous
mixture,
Estimation of vapour pressure.
3.
Material Balances without Chemical Reaction. (6)
Material
balances; Guidelines for solving material balance problems; Material balance of
important
industrial
operations (Distillation, Absorption and Striping, Extraction and Leaching,
Evaporation,
Dryer,
Mixing, Crystallization etc.); Recycle and Bypass operations.
4.
Material Balances with Chemical Reaction. (6)
Definition
of terms involved; Generalized approach for solving problems; Material balance
problems
involving chemical reaction; Electrochemical reactions; Metallurgical
applications;
Recycle,
bypass and purge calculations.
5.
Energy Balance on Non Reactive Processes. (5)
Elements
of energy balance calculations; Change in pressure at constant temperature;
Change in
temperature;
Phase change operations; Mixing and solutions.
6.
Energy Balance on Reactive Processes. (5)
Heat
of reaction; Measurement and calculation of standard heat of reaction, Hess
law; Heat of
formation;
Heat of combustion; Effect of temperature on heat of reaction; adiabatic
reactions.
7.
Combustion.1,5(5)
Minimum
air required, Excess air, Combustion calculations.
8.
Stoichiometry and Industrial problems.1(3)
9.
Introduction to degree of freedom analysis.2(2)
Reference
Books:
1.
Bhatt B.I. and Vora S.M. “Stoichiometry”, Fourth Edition, Tata McGraw-Hill Pub.
Co. Ltd., 2004.
2.
Himmelblau D.M., “Basic Principles and Calculations in Chemical Engineering”,
Sixth Edition,
Prentice-Hall
of India Pvt. Ltd., 2004.
3.
Felder R.M. and Rousseau R.W., “Elementary Principles of Chemical Processes”,
Third Edition,
John
Wiley and Sons, Inc., 2000.
4.
V. Venkataramani and N.Anantharaman., Process Calculations., 2003.
5.
P.L.Ballaney, “Thermal Engineering”.
Note:-
@
Two test of minimum 25 marks each should be conducted for term work.
Figure
in bracket indicates lectures to be conducted
4
HEAT TRANSFER
Teaching
Scheme Examination Scheme
Lectures
: 3 hours / week Theory : 100 Marks
Tutorial
: 1 hours / week Term Work :
Internal
: 25 Marks
External
: 25 Marks
Section
– I
1.
Mechanism of heat flow : Conduction, Convection, Radiation.
2.
Heat transfer by conduction in solids : Fourier's law, steady state heat conduction
through
walls, single and multilayer. Heat flow through a cylinder, Sphere, unsteady
state
heat conduction, equation for one and three dimensional conduction, and
introduction
to semi-infinite solid and critical radius of lagging, Problems.
3.
Principles of heat flow in fluids : Typical heat exchange equipment, co-current and
counter
current flow. Energy balances, rate of heat transfer, overall and individual
heat
transfer
coefficient. Calculation of overall heat transfer co-efficients from individual
heat
transfer coefficients, fouling factors. Transfer units in heat exchangers,
Problems.
4.
Heat transfer to fluids without phase change: Regimes of heat transfer in fluids,
thermal
boundary layer, heat transfer by forced convection in laminar flow. Laminar
flow
heat
transfer to flat plate, the Graetz and Peclet number. Average heat transfer
coefficient
in Laminar flow. Heat transfer by forced convection in turbulent flow,
dimensional
analysis method., effect of tube length, empirical equations, estimation of
wall
temperature, analogy equations. Heat transfer in transition region, heat
transfer to
liquid
metals, heat transfer by forced convection outside tubes, natural convection,
Problems.
Section
– II
5.
Heat transfer to fluids with phase change : Heat transfer from condensing Vapors,
dropwise
and film wise condensation, coefficients for film type condensation, derivation
and
practical use of Nusselt equation, condensation of superheated vapors, effect
of
non-condensable
gases, Problems.
Heat
transfer to boiling liquids : Types of boiling,
boiling of saturated liquid
maximum
flux and critical temperature drop, minimum heat flux film boiling and
subcooled
boiling, Problems.
6.
Heat exchange equipment : Types of heat exchangers, single and multipass
exchangers,
correction of LMTD for cross flow. Simple design calculations of heat
exchangers,
introduction to compact heat exchanger i.e. plate type heat exchanger,
different
types of condensers and boilers, air cooled heat exchangers, introduction to
heat
transfer in agitated vessel, types, construction, definition of fin efficiency,
problems.
7.
Radiation heat transfer : Fundamentals of radiation, wavelength of radiation.
emisivity.Laws
of black body radiation, reflectivity, absorptivity of an opaque solids
,Kirchhoff's
law,radiation between two surfaces. Calculation of radiation between black
surfaces,
combined heat transfer by conduction - convection and radiation, problems.
8.
Evaporation : Liquid
characteristics, types of evaporators, single evaporator capacity
,economy
,boiling point elevation and Duhring's rule. Heat transfer co-efficients,
Enthalpy
balance for single effect evaporator, multiple effect evaporators, types,
methods
of feeding, enthalpy balance of multiple effect evaporator, problems.
9.
Introduction to heat transfer to packed and
fluidized beds: General heat transfer
characteristics,
Calculation for Heat transfer co-efficient.
Term
Work :
1.
Emissivity measurement apparatus.
2.
Natural convection.
3.
Forced convection.
4.
Heat transfer through lagged pipe.
5.
Thermal conductivity of metal rod.
6.
Double pipe heat exchanger.
7.
Packed bed heat exchanger.
8.
Climbing film evaporator.
9.
Heat transfer through agitated vessel.
10.
Shell and tube heat exchanger.
11.
Fin tube heat exchanger.
12.
Compact heat exchanger.
Minimum
10 practicals are to be conducted.
Text
Books:
1.
McCabe W.L., Smith J.C. and Harriott P., “Unit Operations in Chemical
Engineering” , 7th
edition
McGraw Hill,2005.
2.
Sukhatme S.P., “Heat Transfer”,5th edition.,University Press India Ltd.,1996.
References:
1.
William H. Mcadams, “Heat transmission”, 3rd ed. McGraw Hill Series
2.
Alan J. Chapman. “Heat Transfer”, 4th ed. Macmilan Publishing Company, New York
3.
Frank Kreith & Mark S. Bohn. , “Principles of Heat Transfer”, 4th ed. Harper and Row
Publishers,
New York,
4.
Coulson J.M. & Richardson J.F.,”Chemical Engineering” , 3rd ed. Vol.1
5.
J.P. Holman. , “Heat Transfer” , 8th ed. Mc-Graw Hill Inc.1997.
5.
CHEMICAL ENGINEERING THERMODYNAMICS - I
Section
– I
1.
Introduction: Scope
& limitations of thermodynamics, Dimensions and Units, Force
,Temperature
, Pressure, Work energy and Heat, Problems.
2.
First law of thermodynamics and other basic
concepts: Joules experiment, Internal
energy,
First law for non-flow process, Steady state flow processes, Equilibrium, The
phase
rule, Reversible and irreversible processes, Reversible chemical reaction,
Enthalpy,
Heat capacity, Constant volume and pressure process.
3.
Volumetric properties of pure fluids: PVT behavior of pure substances, Virial equation
of
state, Ideal gas temperature, Universal gas constant, Two forms of virial
equation, The
ideal
gas and equations for various processes, Problems, Application of the virial
equation,
Cubic equation of state. The vander wall equation of state, Generalized Cubic
equation
of state. Theorem of corresponding states, Acentric factor.
4.
Heat Effects : Sensible
heat effects, Temperature dependence of heat capacity,
Evaluation
of sensible heat integral, Standard heat of reaction, Standard heat of
formation,
Standard heat of combustion, Temperature dependence of PH0, Heat effects
of
industrial reactions, Problems.
Section
– II
5.
Second law of thermodynamics: Statements, Heat engine, Carnot theorem Ideal gas
temperature
scale, Carnot’s equations,Thermodynamic temperature scale, concept of
Entropy,
Entropy changes of an ideal gas,Significance of Entropy,
Mathematical
statement of second law entropy changes for open system,Third law of
Thermodynamics,
Problems.
6.
Thermodynamic properties of fluids : Property relations for homogeneous phases,
Maxwell’s
relation, Enthalpy and Entropy as functions of temperature and pressure,
Internal
energy as functions of pressure, Ideal gas state, Alternate forms for liquids,
Internal
energy as function of T and V, Gibbs energy as generating function, Residual
properties,
Residual properties by equation of state, Application of thermodynamic
equations
to single phase systems, Two phase systems, Thermodynamic diagrams, P-H
diagram,
H-T diagram, T-S diagram, H-S diagram etc. Thermodynamic charts and
tables.
7.
Application of thermodynamics flow processes : Duct flow of compressible
fluids,
pipe flow, nozzles, throttling process, turbines (expanders), compression
processes,
compressors, pumps, ejectors.
8.
Conversion of heat into work by power cycles : Steam power plant cycle, Internal
combustion
engines, Jet engines,Rocket engines.
9.
Refrigeration and liquefaction : Carnot cycle, Air refregeration and vapor compression
cycles,
Choice of refrigerant. Absorption refrigeration, Heat pump, Liquefaction processes.
Term
Work : Minimum five assignments
covering all problems of the syllabus are to be
Completed
by the students.
Text
Book:
1.
J.M. Smith and H.C. Van Ness, “Introduction to Chemical Engg.”, Thermodynamics
6th Edition,
International
student edition, McGraw Hill publication.
References:
1.
B.F. Dodge, ”Chemical Engg. Thermodynamics”, International student edition
McGraw Hill
Publication.
2.
D.A. Hougen, K.M. Watson and R.A. Ragatz, “Chemical Process Principles”, ( Vol.
II ) 2nd
Edn.
Asia Publishing House.
3.
K.V. Narayanan, “Chemical Engg. Thermodynamics”, Prentice Hall India, New
Delhi.
6.
COMPUTER PRACTICES – II
Teaching
Scheme Examination Scheme
Lectures
: 1 hours / week Practical : 2 hrs/week
Term
Work :
Internal
: 25 Marks
External
: 25 Marks
Programming
in FORTRAN
1.
Programming and writing algorithms: Introduction, Problem Analysis & Algorithm
development,
Algorithm, Flowcharting, Pseudo code, Flowchart And Pseudo code
examples,
Transformation of Pseudo code into a program, Program execution, program
documentation.
2.
Introduction to FORTRAN : Introduction, FORTRAN constants and variables, Type
Declaration,
Integer and real arithmatics, arith operation, the assignment Statement and
arithmetic
expressions and rules for it, FORTRAN statements Diftt statements in
FORTRAN.
3.
Control structures :
Introduction, Selection decision or decision structure, GO TO
statement,
Repetition structure.
4.
Files and I/P O/P : Operations
Introduction : Intro, Files, Programming processes,
various
statements ( e.g. OPEN, CLOSE, READ, WRITE ) Various formats, carriage control.
5.
Arrays : Introduction,
structure of Arrays, Array Declaration, one dimentional
Array,
Multi dimensional Arrays.
6.
Subprograms : Introduction,
function of subprograms statement functions, subroutine
sub
programs, subprogram structure Diagrams, variable Array Dimension, Various
statements
( e.g. Equivalence common, text., Int., Return, Save etc)Block Data
Subprograms.
Term
Work :
1.
Matrix 6. Ascending sorting
2.
Fibonacy numbers 7. Transpose of matrix
3.
Quadratic equations 8. Addition of matrix
4.
Small and large numbers 9. Reverse of given numbers
5.
Descending sorting
Text
Books:
1.
P.S. Grover, “Programming and Computing with Fortran 77/90”, 2nd ed. Allied Publishers
Ltd,
1996.
2.
R.S. Salaria , “Programming in Microsoft Fortan 97”, 2nd ed., BPB Publications, 1994.
3.
K.D. Sharma, “Programming in Fortran”, East-West Press Pvt. Ltd, 1976.
4.
Seymour Lipschutz and Arthur poe, “Programming with Fortran”, Mc-Graw Hill,
1978.
5.
V. Rajaraman, “Computer Programming in Fortran 90 and 95” , Prentice Hall of
India,
1997.
7.
Fluid Moving Machinery Lab.
Lecture:
2 hr. Term work: 25 Marks
Practicals:
2 hr. Oral Exam: 25 Marks
Ch.1)
Centrifugal pumps classification of pumps,
classification of centrifugal pumps, theory of
centrifugal
pump, impellers, casings, volute pumps, volute pumps with vortex chamber,
diffuser
vanes,
work done by centrifugal pumps, developed head of centrifugal pump, efficiency
of
centrifugal
pump, minimum speed for functioning of centrifugal pump, multistage centrifugal
pumps,
pumps in series, pumps in parallel, specific speed of centrifugal pump, model
testing,
suction
lift, priming, binding, cavitation, effect of cavitation, NPSH, calculation of
horse power
requirement,
operating characteristics, comparison, advantages and disadvantages, problems.
Ch
2) Positive displacement pumps classification of
positive displacement pumps,
reciprocating
pumps, volumetric efficiency, single acting, double acting, work done by
reciprocating
pumps, slip of reciprocating pump, variation in velocity and acceleration in
suction
and
discharge line, piston pumps, plunger pump, diaphragm pump, metering pump,
rotary pump,
rotary
gear pump, rotary lobe pump, rotary vane pump, flexible vane pump, peristaltic
pump,
mono
pump.
Ch.
3) Selection of pumps operating conditions, operating
difficulties, comparison between
various
types of pumps, selection criterion in industries, maintenance of pumps.
Ch.
4) Fans, Blowers, and Compressors: Fans,
characteristics, operating pressure conditions,
types
of blowers, positive displacement blower, centrifugal blower, types of
compressors,
centrifugal
compressor, reciprocating compressor, equations for blower and compressors,
adiabatic
compression, isothermal compression, polytrophic compression, compressor
efficiency,
power
equations, vacuum pumps, its working and principle, steam jet ejector, theory
of
compression,
problems.
Textbooks:
1)
Unit Operations of Chemical Engineering, Mc cabe Smith Harriott, McGraw Hill
International
Edition,
Chemical Engineering Series.
2)
Coulson & Richardson’s Chemical Engineering, Volume VI, third edition,
Chemical Engg.
Design.
Reference
books:
1)
Fluid Mechanics by R. P. Vyas, Central Techno Publications, Nagpur.
2)
Design for Chemical and Petrochemical Plants, Ernest E. Ludwig, Volume I &
II, Gulf publishing
Company.
3)
Pumps : G.K.Sahu New age international publishers.
Term
Work : Minimum five assignments
covering all problems of the syllabus are to be
Completed
by the students.
Practicals:
1)
Centrifugal pump test rig
2)
Reciprocating test rig
3)
Demonstration of fans and blowers
4)
Study of centrifugal compressors
5)
Study of gear pumps
6)
Study of vaccum pumps
7)
Study of peristaltic pumps.
SHIVAJI
UNIVERSITY, KOLHAPUR
Equivalence
of S.E.(Chemical Engineering)
Part
I&II
